Derik Hammer has some tips to help you learn about Availability Groups:
3. Use MultiSubnetFailover=true
The Availability Group Listener is technically an optional component of an Availability Group. However, in my opinion it is necessary. By default, your listener will register all IP addresses as DNS A records and it will have multiple IP addresses when your cluster crosses subnets, most commonly when you have disaster recovery between data centers. Using the MultiSubnetFailover=true parameter in your client connection strings will attempt to connect to all IP addresses and completes the connection on the first thread to succeed. The listener ensures that only one IP address is online at a time, therefore you always connect to correct node.
This feature effectively bypasses the limitations of your DNS cache. Traditionally, you would cache the IP address for a DNS record. When you needed the client to connect to a different IP address using the same virtual network name, you would have to wait for the time to live setting to expire. This would delay your recovery time. With the MultiSubnetFailover setting, you can still cache your IP addresses but without the delay that they could induce.
There’s some good reading here.